Origin of the Magnetic Anisotropy in Ni(II) and Co(II) Heptacoordinate Complexes.
Résumé
The nature and magnitude of the magnetic anisotropy of heptacoordinate mononuclear NiII and CoII complexes were investigated by a combination of experiment and ab initio calculations. The zero-field splitting (ZFS) parameters D of [Ni(H2DAPBH)(H2O)2](NO3)2⋅2 H2O (1) and [Co(H2DAPBH)(H2O)(NO3)](NO3) [2; H2DAPBH=2,6-diacetylpyridine bis- (benzoyl hydrazone)] were determined by means of magnetization measurements and high-field high-frequency EPR spectroscopy. The negative D value, and hence an easy axis of magnetization, found for the NiII complex indicates stabilization of the highest MS value of the S=1 ground spin state, while a large and positive D value, and hence an easy plane of magnetization, found for CoII indicates stabilization of the MS=±1/2 sublevels of the S=3/2 spin state. Ab initio calculations were performed to rationalize the magnitude and the sign of D, by elucidating the chemical parameters that govern the magnitude of the anisotropy in these complexes. The negative D value for the NiII complex is due largely to a first excited triplet state that is close in energy to the ground state. This relatively small energy gap between the ground and the first excited state is the result of a small energy difference between the dxy and equation image orbitals owing to the pseudo-pentagonal-bipyramidal symmetry of the complex. For CoII, all of the excited states contribute to a positive D value, which accounts for the large magnitude of the anisotropy for this complex.