Siloxanol-functionalized copper iodide cluster as a thermochromic luminescent building block.

Sandrine Perruchas (1) , Nicolas Desboeufs (1) , Sébastien Maron (1) , X. F Le Goff (2) , Alexandre Fargues (3) , Alain Garcia (3) , Thierry Gacoin (1) , Jean-Pierre Boilot (1)

1 LPMC - Laboratoire de physique de la matière condensée
2 DCPH - Laboratoire Hétéroéléments et Coordination
3 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux

A copper iodide cluster bearing reactive silanol groups exhibits thermochromic luminescence properties sensitive to its chemical environment and is thus a suitable building block for the synthesis of optically active materials.

Mots clés: Thermochromic materials; Iodide; Luminescence; Silanol groups

Domaines: Matériaux

Sandrine Perruchas, Nicolas Desboeufs, Sébastien Maron, X. F Le Goff, Alexandre Fargues, et al.. Siloxanol-functionalized copper iodide cluster as a thermochromic luminescent building block.. Inorganic Chemistry, 2012, 51 (2), pp.794-8. ⟨10.1021/ic200672r⟩. ⟨hal-00763841⟩