Generation and characterization of high-valent iron oxo phthalocyanines

P. Afanasiev (1) , E. V. Kudrik (2) , F. Albrieux , V. Briois , O. I. Koifman , A. B. Sorokin (2)

1 RAFFINAGE - RAFFINAGE
2 BIOVERT - BIOVERT

The first high-valent iron oxo complex on the phthalocyanine platform has been prepared from iron tetra-tert-butyl-phthalocyanine and m-chloroperbenzoic acid and characterized by low temperature UV-vis, cryospray MS, EPR, X-ray absorption and high resolution X-ray emission methods.

Domaines: Catalyse; Environnement et Société

P. Afanasiev, E. V. Kudrik, F. Albrieux, V. Briois, O. I. Koifman, et al.. Generation and characterization of high-valent iron oxo phthalocyanines. Chemical Communications, 2012, 48, pp.6088-6090. ⟨10.1039/c2cc31917a⟩. ⟨hal-00725783⟩