Bifunctional Ligand Approach for Constructing 3d-4f Heterometallic Clusters

Gang Wu (1, 2) , Ian J. Hewitt (1, 2) , Samir Mameri (2) , Yanhua Lan (1) , Rodolphe Clérac (3) , Christopher E. Anson (1) , Shilun Qiu (2) , Annie K. Powell (1)

1 Institut of Inorganic Chemistry
2 State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
3 CRPP - Centre de recherches Paul Pascal

Using a predesigned Schiff-base tripodal ligand, a heptanuclear CuII-GdIII cluster with a spin ground state of S ) 17/2 has been synthesized.

Mots clés: Bifunctional ligand; Heterometallic clusters

Domaines: Chimie inorganique

Gang Wu, Ian J. Hewitt, Samir Mameri, Yanhua Lan, Rodolphe Clérac, et al.. Bifunctional Ligand Approach for Constructing 3d-4f Heterometallic Clusters. Inorganic Chemistry, 2007, 46 (18), pp. 7229-7231. ⟨10.1021/ic070296a⟩. ⟨hal-00700000⟩