Tunable Morphologies From Bulk Self-Assemblies of Poly(acryloxypropyl triethoxysilane)-b-poly(styrene)-b-poly(acryloxypropyl triethoxysilane) Triblock Copolymers

Ce Guinto Gamys (1) , Emmanuel Beyou (1) , Elodie Bourgeat-Lami (2) , Laurent David (1) , Pierre Alcouffe (1)

1 IMP-LMPB - Ingénierie des Matériaux Polymères - Laboratoire des Matériaux Polymères et des Biomatériaux
2 C2P2 - Laboratoire de Chimie, Catalyse, Polymères et Procédés, R 5265

Reactive poly(acryloxypropyl triethoxysilane)-b-poly(styrene)-b-poly(acryloxypropyl triethoxysilane) (PAPTES-b-PS-b-PAPTES) triblock copolymers are prepared through nitroxide-mediated polymerization (NMP). The bulk morphologies formed by this class of copolymers cast into films are examined by small-angle X-ray scattering (SAXS) and transmission electron microscopy (TEM). The films morphology can be tuned from spherical structures to lamellar structures by increasing the volume fraction of PS in the copolymer. Thermal annealing at temperatures above 100 degrees C provides sufficient PS mobility to improve ordering.

Mots clés: block copolymers; gelable triblock copolymers; self-assembly; small-angle X-ray scattering; transmission electron microscopy

Domaines: Polymères; Matériaux

Ce Guinto Gamys, Emmanuel Beyou, Elodie Bourgeat-Lami, Laurent David, Pierre Alcouffe. Tunable Morphologies From Bulk Self-Assemblies of Poly(acryloxypropyl triethoxysilane)-b-poly(styrene)-b-poly(acryloxypropyl triethoxysilane) Triblock Copolymers. Macromolecular Chemistry and Physics, 2012, 213, pp.10-18. ⟨10.1002/macp.201100507⟩. ⟨hal-00692018⟩