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Article Dans Une Revue Journal of Polymer Science Part A: Polymer Chemistry Année : 2012

Crosslinked polynorbornene particles synthesis by ring-opening metathesis polymerization in dispersion

Résumé

This article proposes the first report on the synthesis of nanometric crosslinked polynorbornene particles by ring-opening metathesis polymerization in dispersion using ruthenium-based complex (PCy3)2Cl2Ru=CHPh as initiator. Stable but raspberry-shaped particles were obtained. In this study, a particular attention was paid to the influence of the crosslinker nature and addition mode on reaction kinetics and morphology of the latex particles.

Dates et versions

hal-00684060 , version 1 (30-03-2012)

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Anne-Claire Le Meur, Cyril Aymonier, Valérie Héroguez. Crosslinked polynorbornene particles synthesis by ring-opening metathesis polymerization in dispersion. Journal of Polymer Science Part A: Polymer Chemistry, 2012, 50 (9), pp.1746-1754. ⟨10.1002/pola.25941⟩. ⟨hal-00684060⟩
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