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Reaction of anthracene with CH radicals: an experimental study of the kinetics between 58 and 470 K.

Abstract : The rate coefficient of the reaction of the methylidine radical CH with anthracene has been studied over a wide temperature range (58-470 K) in a dedicated "Cinétique de Réaction en Ecoulement Supersonique Uniforme" (Reaction Kinetics in Uniform Supersonic Flow) apparatus. The reaction exhibits a slight positive temperature dependence, which can be fitted to the expression k(T) = (3.32 +/- 1.00) x 10(-10)(T/298)((0.46+/-0.14)) cm3 molecule(-1) s(-1). Even at the lowest temperature, the reaction remains very fast indicating that the kinetics are probably driven by a capture process.
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https://hal.archives-ouvertes.fr/hal-00653283
Contributor : Dorothée Destouches <>
Submitted on : Monday, December 19, 2011 - 11:34:51 AM
Last modification on : Tuesday, January 12, 2021 - 4:40:54 PM

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Fabien Goulay, Christiane Rebrion-Rowe, Ludovic Biennier, Sébastien D Le Picard, André Canosa, et al.. Reaction of anthracene with CH radicals: an experimental study of the kinetics between 58 and 470 K.. Journal of Physical Chemistry A, American Chemical Society, 2006, 110 (9), pp.3132-7. ⟨10.1021/jp054537g⟩. ⟨hal-00653283⟩

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