Zinc-Adeninate Metal-Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations

Abstract : Luminescent metal-organic frameworks (MOFs), Ln(3+)@bio-MOF-1, were synthesized via post-synthetic cation exchange of bio-MOF-1 with Tb3+, Sm3+, Eu3+, or Yb3+, and their photophysical properties were studied. We demonstrate that bio-MOF-1 encapsulates and sensitizes visible and near-infrared emitting lanthanide cations in aqueous solution.
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https://hal.archives-ouvertes.fr/hal-00608199
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Submitted on : Tuesday, July 12, 2011 - 2:14:24 PM
Last modification on : Thursday, April 18, 2019 - 1:05:56 PM

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Jihyun Y. An, Chad M. Shade, Demetra A. Chengelis-Czegan, Stéphane Petoud, Nathaniel L. Rosi. Zinc-Adeninate Metal-Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations. Journal of the American Chemical Society, American Chemical Society, 2011, 133 (5), pp.1220-1223. ⟨10.1021/ja109103t⟩. ⟨hal-00608199⟩

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