V. @bullet, + (24); m/z 243 [M-C 3 H 8 -TMSOH-CO-CH ? 3, pp.204-83

M. R. Alfarra, D. Paulsen, M. Gysel, A. A. Garforth, J. Dommen et al., A mass spectrometric study of secondary organic aerosols formed from the photooxidation of anthropogenic and biogenic precursors in a reaction chamber, Atmos. Chem. Phys, vol.65194, pp.5279-529310, 2006.
URL : https://hal.archives-ouvertes.fr/hal-00296078

C. Baduel, D. Voisin, and J. L. Jaffrezo, Comparison of analytical methods for HULIS measurements in atmospheric particles, Atmospheric Chemistry and Physics Discussions, vol.9, issue.2, pp.6787-682510, 2009.
DOI : 10.5194/acpd-9-6787-2009

URL : https://hal.archives-ouvertes.fr/insu-00497814

C. Baduel, Fraction organique de l'aerosol : quantification et caractérisation de la fraction Humic LIke, 2010.

C. Baduel, D. Voisin, and J. L. Jaffrezo, Seasonal variations of concentrations and optical properties of water soluble HULIS collected in urban environments, Atmospheric Chemistry and Physics, vol.10, issue.9, pp.4085-4095, 2004.
DOI : 10.5194/acp-10-4085-2010

URL : https://hal.archives-ouvertes.fr/insu-00553584

M. E. Birch, C. , and R. A. , Elemental Carbon-Based Method for Monitoring Occupational Exposures to Particulate Diesel Exhaust, Aerosol Science and Technology, vol.14, issue.3, pp.221-241, 1996.
DOI : 10.1080/15298669191365162

A. G. Carlton, C. Wiedinmyer, and J. H. Kroll, A review of Secondary Organic Aerosol (SOA) formation from isoprene, Atmos . Chem. Phys, vol.95194, pp.4987-500510, 2009.

M. Claeys, B. Graham, G. Vas, W. Wang, R. Vermeylen et al., Formation of Secondary Organic Aerosols Through Photooxidation of Isoprene, Science, vol.303, issue.5661, pp.1173-1176, 2004.
DOI : 10.1126/science.1092805

M. Claeys, W. Wang, A. C. Ion, I. Kourtchev, A. Gelencser et al., Formation of secondary organic aerosols from isoprene and its gas-phase oxidation products through reaction with hydrogen peroxide, Atmospheric Environment, vol.38, issue.25, pp.4093-4098, 2004.
DOI : 10.1016/j.atmosenv.2004.06.001

M. Claeys, R. Szmigielski, I. Kourtchev, P. Van-der-veken, R. Vermeylen et al., Hydroxydicarboxylic Acids:?? Markers for Secondary Organic Aerosol from the Photooxidation of ??-Pinene, Environmental Science & Technology, vol.41, issue.5, pp.1628-1634, 2007.
DOI : 10.1021/es0620181

J. De-gouw and C. Warneke, Measurements of volatile organic compounds in the earth's atmosphere using proton-transfer-reaction mass spectrometry, Mass Spectrometry Reviews, vol.38, issue.224, pp.223-257, 2007.
DOI : 10.1002/mas.20119

J. A. De-gouw, P. D. Goldan, C. Warneke, W. C. Kuster, J. M. Roberts et al., Validation of proton transfer reaction-mass spectrometry (PTR-MS) measurements of gas-phase organic compounds in the atmosphere during the New England Air Quality Study (NEAQS) in, J. Geophys. Res.-Atmos, vol.108, p.468210, 1029.

X. Ding, M. Zheng, L. P. Yu, X. L. Zhang, R. J. Weber et al., Spatial and Seasonal Trends in Biogenic Secondary Organic Aerosol Tracers and Water-Soluble Organic Carbon in the Southeastern United States, Environmental Science & Technology, vol.42, issue.14, pp.5171-5176, 2008.
DOI : 10.1021/es7032636

N. M. Donahue, A. L. Robinson, C. O. Stanier, and S. N. Pandis, Coupled Partitioning, Dilution, and Chemical Aging of Semivolatile Organics, Environmental Science & Technology, vol.40, issue.8, pp.2635-264310, 2006.
DOI : 10.1021/es052297c

J. Dron, G. Eyglunent, B. Temime-roussel, N. Marchand, and H. Wortham, Carboxylic acid functional group analysis using constant neutral loss scanning-mass spectrometry, Analytica Chimica Acta, vol.605, issue.1, pp.61-69, 2007.
DOI : 10.1016/j.aca.2007.10.020

J. Dron, W. Zheng, N. Marchand, and H. Wortham, New method to determine the total carbonyl functional group content in extractable particulate organic matter by tandem mass spectrometry, Journal of Mass Spectrometry, vol.6, issue.8, pp.1089-1098, 2008.
DOI : 10.1002/jms.1392

J. Dron, E. Abidi, I. Haddad, N. Marchand, and H. Wortham, Precursor ion scanning???mass spectrometry for the determination of nitro functional groups in atmospheric particulate organic matter, Analytica Chimica Acta, vol.618, issue.2, pp.184-195, 2008.
DOI : 10.1016/j.aca.2008.04.057

E. Haddad, I. Marchand, N. Wortham, H. Piot, C. Besombes et al., Primary sources of PM 2.5 organic aerosol in an industrial Mediterranean city, Atmos. Chem. Phys, vol.115194, pp.2039-205810, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00608056

T. Feczko, H. Puxbaum, A. Kasper-giebl, M. Handler, A. Limbeck et al., Determination of water and alkaline extractable atmospheric humiclike substances with the TU Vienna HULIS analyzer in samples from six background sites in Europe, J. Geophys. Res.-Atmos, vol.112, pp.23-1010, 1029.
URL : https://hal.archives-ouvertes.fr/insu-00376271

A. Gelencser, B. May, D. Simpson, A. Sanchez-ochoa, A. Kasper-giebl et al., Source apportionment of PM 2.5 organic aerosol over Europe: Primary/secondary, natural/anthropogenic, and fossil/biogenic origin, J. Geophys. Res.-Atmos, vol.112, pp.23-0410, 1029.
URL : https://hal.archives-ouvertes.fr/insu-00376309

A. H. Goldstein and I. E. Galbally, Known and Unexplored Organic Constituents in the Earth's Atmosphere, Environmental Science & Technology, vol.41, issue.5, pp.1514-1521, 2007.
DOI : 10.1021/es072476p

A. P. Grieshop, N. M. Donahue, R. , and A. L. , Laboratory investigation of photochemical oxidation of organic aerosol from wood fires 2: analysis of aerosol mass spectrometer data, Atmos . Chem. Phys, vol.95194, pp.2227-224010, 2009.

A. P. Grieshop, J. M. Logue, N. M. Donahue, R. , and A. L. , Laboratory investigation of photochemical oxidation of organic aerosol from wood fires 1: measurement and simulation of organic aerosol evolution, Atmos. Chem. Phys, vol.95194, pp.1263-127710, 1263.

M. Hallquist, J. C. Wenger, U. Baltensperger, Y. Rudich, D. Simpson et al., The formation, properties and impact of secondary organic aerosol: current and emerging issues, Atmos . Chem. Phys, vol.95194, pp.5155-523610, 2009.
URL : https://hal.archives-ouvertes.fr/hal-00431138

J. F. Hamilton, P. J. Webb, A. C. Lewis, J. R. Hopkins, S. Smith et al., Partially oxidised organic components in urban aerosol using GCXGC-TOF/MS, Atmos. Chem. Phys, vol.45194, pp.1279-129010, 1279.
URL : https://hal.archives-ouvertes.fr/hal-00295481

C. L. Heald, D. J. Jacob, R. J. Park, L. M. Russell, B. J. Huebert et al., A large organic aerosol source in the free troposphere missing from current models, Geophysical Research Letters, vol.14, issue.1, 2005.
DOI : 10.1029/2005GL023831

L. Hildebrandt, G. J. Engelhart, C. Mohr, E. Kostenidou, V. A. Lanz et al., Aged organic aerosol in the Eastern Mediterranean: the Finokalia Aerosol Measurement Experiment-2008, Atmos. Chem. Phys, vol.105194, pp.4167-418610, 2010.

A. Hodzic, J. L. Jimenez, A. S. Prévôt, S. Szidat, J. D. Fast et al., Can 3-D models explain the observed fractions of fossil and non-fossil carbon in and near Mexico City?, Atmos. Chem. Phys, vol.105194, pp.10997-1101610, 2010.

A. C. Ion, R. Vermeylen, I. Kourtchev, J. Cafmeyer, X. Chi et al., Polar organic compounds in rural PM<sub>2.5</sub> aerosols from K-puszta, Hungary, during a 2003 summer field campaign: Sources and diel variations, Atmospheric Chemistry and Physics, vol.5, issue.7, pp.1805-181410, 1805.
DOI : 10.5194/acp-5-1805-2005

J. Jaffrezo, G. Aymoz, C. Delaval, C. , and J. , Seasonal variations of the water soluble organic carbon mass fraction of aerosol in two valleys of the French Alps, Atmos. Chem. Phys, vol.55194, pp.2809-282110, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00328407

J. L. Jaffrezo, T. Calas, and M. Bouchet, Carboxylic acids measurements with ionic chromatography, Atmospheric Environment, vol.32, issue.14-15, pp.2705-2708, 1998.
DOI : 10.1016/S1352-2310(98)00026-0

M. Jaoui, T. E. Kleindienst, M. Lewandowski, J. H. Offenberg, and E. O. Edney, Identification and Quantification of Aerosol Polar Oxygenated Compounds Bearing Carboxylic or Hydroxyl Groups. 2. Organic Tracer Compounds from Monoterpenes, Environmental Science & Technology, vol.39, issue.15, pp.5661-5673, 2005.
DOI : 10.1021/es048111b

M. Jaoui, M. Lewandowski, T. E. Kleindienst, J. H. Offenberg, and E. O. Edney, beta-caryophyllinic acid: An atmospheric tracer for beta-caryophyllene secondary organic aerosol, Geophys . Res. Lett, vol.34, 2007.

J. L. Jimenez, M. R. Canagaratna, N. M. Donahue, A. S. Prevot, Q. Zhang et al., Evolution of Organic Aerosols in the Atmosphere, and Worsnop, D. R.: Evolution of organic aerosols in the atmosphere, pp.1525-1529, 2009.
DOI : 10.1126/science.1180353

M. Kanakidou, J. H. Seinfeld, S. N. Pandis, I. Barnes, F. J. Dentener et al., Organic aerosol and global climate modelling: A review, Atmos . Chem. Phys, vol.55194, pp.1053-112310, 1053.
DOI : 10.5194/acpd-4-5855-2004

URL : https://hal.archives-ouvertes.fr/hal-00328384

L. Ke, X. Ding, R. L. Tanner, J. J. Schauer, and M. Zheng, Source contributions to carbonaceous aerosols in the Tennessee Valley Region, Atmospheric Environment, vol.41, issue.39, pp.8898-8923, 2007.
DOI : 10.1016/j.atmosenv.2007.08.024

S. H. Kessler, J. D. Smith, D. L. Che, D. R. Worsnop, K. R. Wilson et al., Chemical Sinks of Organic Aerosol: Kinetics and Products of the Heterogeneous Oxidation of Erythritol and Levoglucosan, Environmental Science & Technology, vol.44, issue.18, pp.7005-7010, 2010.
DOI : 10.1021/es101465m

T. E. Kleindienst, M. Jaoui, M. Lewandowski, J. H. Offenberg, C. W. Lewis et al., Estimates of the contributions of biogenic and anthropogenic hydrocarbons to secondary organic aerosol at a southeastern US location, Atmospheric Environment, vol.41, issue.37, pp.8288-8300, 2007.
DOI : 10.1016/j.atmosenv.2007.06.045

T. E. Kleindienst, M. Lewandowski, J. H. Offenberg, M. Jaoui, and E. O. Edney, The formation of secondary organic aerosol from the isoprene plus OH reaction in the absence of NOx

I. Kourtchev, J. Warnke, W. Maenhaut, T. Hoffmann, and M. Claeys, Polar organic marker compounds in PM 2.5 aerosol from a mixed forest site in western Germany, Chemosphere, pp.73-1308, 2008.

I. Kourtchev, L. Copolovici, M. Claeys, and W. Maenhaut, Characterization of Atmospheric Aerosols at a Forested Site in Central Europe, Environmental Science & Technology, vol.43, issue.13, pp.4665-4671, 2009.
DOI : 10.1021/es803055w

J. H. Kroll, N. L. Ng, S. M. Murphy, R. C. Flagan, and J. H. Seinfeld, Secondary organic aerosol formation from isoprene photooxidation under high-NOx conditions, Geophys. Res. Lett, pp.10-1029, 2005.

J. H. Kroll, N. L. Ng, S. M. Murphy, R. C. Flagan, and J. H. Seinfeld, Secondary Organic Aerosol Formation from Isoprene Photooxidation, Environmental Science & Technology, vol.40, issue.6, pp.1869-1877, 2006.
DOI : 10.1021/es0524301

W. C. Kuster, B. T. Jobson, T. Karl, D. Riemer, E. Apel et al., Intercomparison of Volatile Organic Carbon Measurement Techniques and Data at La Porte during the TexAQS2000 Air Quality Study, Environmental Science & Technology, vol.38, issue.1, pp.221-228, 2004.
DOI : 10.1021/es034710r

N. Lang-yona, Y. Rudich, T. F. Mentel, A. Bohne, A. Buchholz et al., The chemical and microphysical properties of secondary organic aerosols from Holm Oak emissions

M. Legrand, S. Preunkert, T. Oliveira, C. A. Pio, S. Hammer et al., Origin of C-2-C-5 dicarboxylic acids in the European atmosphere inferred from year-round aerosol study conducted at a west- 10, J. Geophys. Res.-Atmos, vol.112, pp.23-0710, 1029.

I. Levin, B. Kromer, H. Schochfischer, M. Bruns, M. Munnich et al., years of tropospheric C-14 observations in central-Europe, Radiocarbon, vol.27, pp.25-26, 1985.

I. Levin and V. Hesshaimer, Radiocarbon ??? A Unique Tracer of Global Carbon Cycle Dynamics, Radiocarbon, vol.44, issue.01, pp.69-80, 2000.
DOI : 10.1111/j.2153-3490.1975.tb01671.x

M. Lewandowski, M. Jaoui, J. H. Offenberg, T. E. Kleindienst, E. O. Edney et al., Primary and Secondary Contributions to Ambient PM in the Midwestern United States, Environmental Science & Technology, vol.42, issue.9, pp.3303-3309, 2008.
DOI : 10.1021/es0720412

W. Lindinger, A. Hansel, J. , and A. , On-line monitoring of volatile organic compounds at pptv levels by means of proton-transfer-reaction mass spectrometry (PTR-MS) medical applications, food control and environmental research, International Journal of Mass Spectrometry and Ion Processes, vol.173, issue.3, pp.191-241, 1998.
DOI : 10.1016/S0168-1176(97)00281-4

S. A. Montzka, M. Trainer, P. D. Goldan, W. C. Kuster, and F. C. Fehsenfeld, Isoprene and its oxidation products, methyl vinyl ketone and methacrolein, in the rural troposphere, Journal of Geophysical Research: Atmospheres, vol.93, issue.D1, pp.1101-1111, 1993.
DOI : 10.1029/92JD02382

N. L. Ng, J. H. Kroll, M. D. Keywood, R. Bahreini, V. Varutbangkul et al., Contribution of First- versus Second-Generation Products to Secondary Organic Aerosols Formed in the Oxidation of Biogenic Hydrocarbons, Environmental Science & Technology, vol.40, issue.7, pp.2283-2297, 2006.
DOI : 10.1021/es052269u

S. M. Owen, P. Harley, A. Guenther, H. , and C. N. , Light dependency of VOC emissions from selected Mediterranean plant species, Atmospheric Environment, vol.36, issue.19, pp.3147-3159, 2002.
DOI : 10.1016/S1352-2310(02)00235-2

R. Parra, S. Gasso, and J. M. Baldasano, Estimating the biogenic emissions of non-methane volatile organic compounds from the North Western Mediterranean vegetation of Catalonia, Spain, Science of The Total Environment, vol.329, issue.1-3, pp.241-259, 2004.
DOI : 10.1016/j.scitotenv.2004.03.005

F. Paulot, J. D. Crounse, H. G. Kjaergaard, A. Kurten, J. M. St-clair et al., Unexpected Epoxide Formation in the Gas-Phase Photooxidation of Isoprene, Science, vol.325, issue.5941, pp.730-733, 2009.
DOI : 10.1126/science.1172910

A. L. Robinson, N. M. Donahue, M. K. Shrivastava, E. A. Weitkamp, A. M. Sage et al., Rethinking Organic Aerosols: Semivolatile Emissions and Photochemical Aging, Science, vol.315, issue.5816, pp.315-1259, 2007.
DOI : 10.1126/science.1133061

J. F. Rontani and C. Aubert, Trimethylsilyl transfer during electron ionization mass spectral fragmentation of some??-hydroxycarboxylic and??-dicarboxylic acid trimethylsilyl derivatives and the effect of chain length, Rapid Communications in Mass Spectrometry, vol.18, issue.17, pp.1889-1895, 2004.
DOI : 10.1002/rcm.1567

L. M. Russell, L. N. Hawkins, A. A. Frossard, P. K. Quinn, and T. S. Bates, Carbohydrate-like composition of submicron atmospheric particles and their production from ocean bubble bursting, Proceedings of the National Academy of Sciences, vol.107, issue.15, pp.6652-6657, 2010.
DOI : 10.1073/pnas.0908905107

A. M. Sage, E. A. Weitkamp, A. L. Robinson, and N. M. Donahue, Evolving mass spectra of the oxidized component of organic aerosol: results from aerosol mass spectrometer analyses of aged diesel emissions, Atmos. Chem. Phys, vol.85194, pp.1139-115210, 1139.
URL : https://hal.archives-ouvertes.fr/hal-00296467

J. J. Schauer, W. F. Rogge, L. M. Hildemann, M. A. Mazurek, G. R. Cass et al., Source apportionment of airborne particulate matter using organic compounds as tracers, Atmospheric Environment, vol.30, issue.22, pp.3837-3855, 1996.
DOI : 10.1016/1352-2310(96)00085-4

J. J. Schauer and G. R. Cass, Source Apportionment of Wintertime Gas-Phase and Particle-Phase Air Pollutants Using Organic Compounds as Tracers, Environmental Science & Technology, vol.34, issue.9, pp.1821-1832, 2000.
DOI : 10.1021/es981312t

J. J. Schauer, M. P. Fraser, G. R. Cass, and B. R. Simoneit, Source Reconciliation of Atmospheric Gas-Phase and Particle-Phase Pollutants during a Severe Photochemical Smog Episode, Environmental Science & Technology, vol.36, issue.17, pp.3806-3814, 2002.
DOI : 10.1021/es011458j

H. Schmid, L. Laskus, J. Abraham, H. Baltensperger, U. Lavanchy et al., Results of the ???carbon conference??? international aerosol carbon round robin test stage I, Atmospheric Environment, vol.35, issue.12, pp.2111-2121, 2001.
DOI : 10.1016/S1352-2310(00)00493-3

V. Simon, L. Dumergues, J. L. Ponche, and L. Torres, The biogenic volatile organic compounds emission inventory in France, Science of The Total Environment, vol.372, issue.1, pp.164-182, 2006.
DOI : 10.1016/j.scitotenv.2006.08.019

URL : https://hal.archives-ouvertes.fr/hal-00136570

R. Steinbrecher, G. Smiatek, R. Koble, G. Seufert, J. Theloke et al., Intra- and inter-annual variability of VOC emissions from natural and semi-natural vegetation in Europe and neighbouring countries, Atmospheric Environment, vol.43, issue.7, pp.1380-1391, 2009.
DOI : 10.1016/j.atmosenv.2008.09.072

E. A. Stone, D. C. Snyder, R. J. Sheesley, A. P. Sullivan, R. J. Weber et al., Source apportionment of fine organic aerosol in Mexico City during the MILAGRO experiment, Atmos. Chem. Phys, vol.85194, pp.1249-125910, 1249.
URL : https://hal.archives-ouvertes.fr/hal-00296472

E. A. Stone, J. B. Zhou, D. C. Snyder, A. P. Rutter, M. Mieritz et al., A Comparison of Summertime Secondary Organic Aerosol Source Contributions at Contrasting Urban Locations, Environmental Science & Technology, vol.43, issue.10, pp.3448-3454, 2009.
DOI : 10.1021/es8025209

J. D. Surratt, S. M. Murphy, J. H. Kroll, N. L. Ng, L. Hildebrandt et al., Chemical Composition of Secondary Organic Aerosol Formed from the Photooxidation of Isoprene, The Journal of Physical Chemistry A, vol.110, issue.31, pp.9665-9690, 2006.
DOI : 10.1021/jp061734m

J. D. Surratt, M. Lewandowski, J. H. Offenberg, M. Jaoui, T. E. Kleindienst et al., Effect of Acidity on Secondary Organic Aerosol Formation from Isoprene, Environmental Science & Technology, vol.41, issue.15
DOI : 10.1021/es0704176

J. D. Surratt, Y. Gomez-gonzalez, A. W. Chan, R. Vermeylen, M. Shahgholi et al., Organosulfate Formation in Biogenic Secondary Organic Aerosol, The Journal of Physical Chemistry A, vol.112, issue.36, pp.8345-8378, 2008.
DOI : 10.1021/jp802310p

R. Szmigielski, J. D. Surratt, Y. Gomez-gonzalez, P. Van-der-veken, I. Kourtchev et al., acid: An atmospheric tracer for terpene secondary organic aerosol, Geophys. Res. Lett, vol.32, issue.1, pp.3-10, 1029.

R. L. Tanner, W. J. Parkhurst, and A. P. Mcnichol, on Findings from the Fine Particulate Matter Supersites Program, Aerosol Science and Technology, vol.38, issue.sup1, pp.133-139, 2004.
DOI : 10.1080/02786820390229453

J. Zhao and R. Y. Zhang, Proton transfer reaction rate constants between hydronium ion (H3O+) and volatile organic compounds, Atmospheric Environment, vol.38, issue.14, pp.2177-2185, 2004.
DOI : 10.1016/j.atmosenv.2004.01.019

M. Zheng, L. Ke, E. S. Edgerton, J. J. Schauer, M. Y. Dong et al., Spatial distribution of carbonaceous aerosol in the southeastern United States using molecular markers and carbon isotope data, Journal of Geophysical Research: Atmospheres, vol.39, issue.D21, pp.10-0610, 2006.
DOI : 10.1029/2005JD006777