Autocatalytic sonolysis of iron pentacarbonyl in room temperature ionic liquid [BuMeIm][Tf2N]

Abstract : The autocatalytic sonochemical reaction of Fe(CO)5 decomposition in [BuMeIm][Tf2N] provides iron nanoparticles in higher yields than in tetralin. Such a difference is explained by the higher decomposition of the intermediate Fe3(CO)12 according to the two-sites model of the sonochemical reactions and the specific properties of the ionic liquid.
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Submitted on : Sunday, February 20, 2011 - 10:13:30 PM
Last modification on : Tuesday, May 28, 2019 - 2:06:12 PM

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Lenaïc Lartigue, Rachel Pflieger, Sergey Nikitenko, Yannick Guari, Lorenzo Stievano, et al.. Autocatalytic sonolysis of iron pentacarbonyl in room temperature ionic liquid [BuMeIm][Tf2N]. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2010, 13, pp.2111-2113. ⟨10.1039/C0CP01670E⟩. ⟨hal-00567345⟩

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