A New synthesis of alkane and polyfluoroalkanesulfonyl chlorides

Zohra Benfodda (1) , Franck Guillen (2) , Hélène Armion (1) , Abdelkader Dahmani (1) , Hubert Blancou (1)

1 IBMM - Institut des Biomolécules Max Mousseron [Pôle Chimie Balard]
2 S3F Chimie

This study describes a new and advantageous procedure for the synthesis of alkanesulfonyl chlorides (2) by the reaction of alkyl thiocyanates (1) with sulfuryl chloride in a mixture of acetic acid and water. The alkanesulfonyl chlorides were obtained in good yields.

Domaines: Chimie organique

Zohra Benfodda, Franck Guillen, Hélène Armion, Abdelkader Dahmani, Hubert Blancou. A New synthesis of alkane and polyfluoroalkanesulfonyl chlorides. Heteroatom Chemistry, 2009, 20 (6), pp.355-361. ⟨10.1002/hc.20559⟩. ⟨hal-00555938⟩