White phosphorus and metal nanoparticles: a versatile route to metal phosphide nanoparticles. (pub)

Sophie Carenco (1, 2) , Matthieu Demange (1) , Jing Shi (1) , Cédric Boissière (2) , Clément Sanchez (2) , Pascal Le Floch (1) , Nicolas Mézailles (1)

1 DCPH - Laboratoire Hétéroéléments et Coordination
2 LCMCP (site Paris VI) - Laboratoire de Chimie de la Matière Condensée de Paris (site Paris VI)

P(4) reaction with metal NPs (In, Pb, Zn) provides an easy access to the corresponding metal phosphide NPs in a soft and stoichiometric reaction. Size-influence on the reactivity is investigated in the case of indium.

Domaines: Catalyse; Matériaux

Sophie Carenco, Matthieu Demange, Jing Shi, Cédric Boissière, Clément Sanchez, et al.. White phosphorus and metal nanoparticles: a versatile route to metal phosphide nanoparticles. (pub). Chemical Communications, 2010, 46 (30), pp.5578-80. ⟨10.1039/c0cc00684j⟩. ⟨hal-00534103⟩