The Metallic Compound Sr0.44La0.56Mo5O8

Philippe Gall (1) , Patrick Gougeon (2) , W.H. Mc Carroll

1 MICDR - Sciences Chimiques de Rennes / Matériaux Inorganiques: Chimie Douce et Réactivité
2 ISCR - Institut des Sciences Chimiques de Rennes

Strontium lanthanum pentamolybdenum octaoxide, Sr0.44La0.56Mo5O8, belongs to the AMo5O8 structure type (A = Ca, Sr, Sn, Pb, Eu, La to Gd). Its crystal structure consists of bioctahedral Mo10O18 cluster units interconnected through Mo-Mo bonds of 2.7322 (7) Å to form infinite molybdenum oxide chains. These are linked by corner O atoms to create four-sided channels along [100], in which the La3+ and Sr2+ cations are statistically distributed over one unique position

Domaines: Chimie inorganique

Philippe Gall, Patrick Gougeon, W.H. Mc Carroll. The Metallic Compound Sr0.44La0.56Mo5O8. Acta crystallographica Section E : Crystallographic communications [2015-..], 2007, E63, pp.i119-i121. ⟨hal-00525380⟩