Synthesis of phosphorylated calix[4]arene derivatives for the design of solid phases immobilizing uranyl cations.

Agnes Hagege (1) , Zouhair Asfari (1) , Elias Bou-Maroun (1) , Eric Quéméneur (2) , Claude Vidaud (2)

1 DSA-IPHC - Département Sciences Analytiques et Interactions Ioniques et Biomoléculaires
2 SBTN - Service de Biochimie et Toxicologie Nucléaire

With the aim of developing supports for uranyl cations immobilization, new 1,3-alternate calix[4]arenes bearing both phosphonic acid functions as chelating sites and N-succinimide-4-oxabutyrate as the anchoring arm were synthesized in good yields. The coupling of such calixarenes to a gel was performed and a successful immobilization of uranyl cations was obtained.

Mots clés: Physical Sciences

Domaines: Chimie

Agnes Hagege, Zouhair Asfari, Elias Bou-Maroun, Eric Quéméneur, Claude Vidaud. Synthesis of phosphorylated calix[4]arene derivatives for the design of solid phases immobilizing uranyl cations.. Supramolecular Chemistry, 2009, 21 (07), pp.585-590. ⟨10.1080/10610270802588301⟩. ⟨hal-00520014⟩