Temperatures of liquid–liquid separation and excess molar volumes of {N-methylpiperidine–water} and 2-methylpiperidine–water} systems

Abstract : Partial miscibility in binary systems {N-methylpiperidine–water} and {2-methylpiperidine–water} was studied. The temperatures of liquid–liquid separation were determined as function of composition using both calorimetric technique and phase equilibrium cell. The densities of {amine–water} mixtures were determined in the domain of total miscibility at temperatures between 288K and 338 K. Excess molar volumes were derived from experimental density data and fit to a Redlich–Kister polynomial.
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https://hal.archives-ouvertes.fr/hal-00484637
Contributor : Karine Ballerat-Busserolles <>
Submitted on : Tuesday, May 18, 2010 - 5:03:01 PM
Last modification on : Thursday, March 15, 2018 - 3:44:02 PM

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Yohann Coulier, Karine Ballerat-Busserolles, Laurence Rodier, Jean Yves Coxam. Temperatures of liquid–liquid separation and excess molar volumes of {N-methylpiperidine–water} and 2-methylpiperidine–water} systems. Fluid Phase Equilibria, Elsevier, 2010, 296, pp.206-212. ⟨10.1016/j.fluid.2010.05.001⟩. ⟨hal-00484637⟩

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