Aspects of the Coordination Chemistry of 1,1'-Di(benzothiazol-2-ylthio)ferrocene

Ulrich Siemeling (1) , Alexander Girod (1) , Dag Rother (1) , Clemens Bruhn (1)

1 Institut für Chemie

1,1'-Di(benzothiazol-2-ylthio)ferrocene (1) acts as a bridging bidentate N,N-ligand and affords coordination polymers with a range of CuI, AgI, CuII, ZnII and HgII salts. The crystal structures of [Ag(CF3SO3)(-1)]n, [CuCl2(-1)]n, [ZnCl2(-1)]n and [HgBr2(-1)]n have been determined. The silver atom exhibits a weak contact to a cyclopentadienyl -system in addition to its trigonal-planar coordination. The copper atom is in a square-planar coordination environment, while the coordination of zinc and mercury is best described as distorted tetrahedral in the corresponding complexes.

Mots clés: Physical Sciences

Ulrich Siemeling, Alexander Girod, Dag Rother, Clemens Bruhn. Aspects of the Coordination Chemistry of 1,1'-Di(benzothiazol-2-ylthio)ferrocene. Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie, 2009, 635 (9-10), pp.1402. ⟨10.1002/zaac.200900084⟩. ⟨hal-00479611⟩