Double geminal C-H activation and reversible α-elimination in 2-aminopyridine iridium(III) complexes: The role of hydrides and solvent in flattening the free energy surface

Eric Clot (1) , Junyi Chen (2) , Dong-Heon Lee (3) , So Young Sung (3) , Leah N. Appelhans (2) , Jack W. Faller (2) , Robert H. Crabtree (2) , Odile Eisenstein (1)

1 LSDSMS - Laboratoire de structure et de dynamique des systèmes moléculaires et solides
2 Department of Chemistry [New Haven]
3 Department of Chemistry

Domaines: Chimie-Physique [physics.chem-ph]

Eric Clot, Junyi Chen, Dong-Heon Lee, So Young Sung, Leah N. Appelhans, et al.. Double geminal C-H activation and reversible α-elimination in 2-aminopyridine iridium(III) complexes: The role of hydrides and solvent in flattening the free energy surface. Journal of the American Chemical Society, 2004, 126, pp.8795-8804. ⟨10.1021/ja048473j⟩. ⟨hal-00429085⟩