Dramatic solid-state humidity-induced modification of the magnetic coupling in a dimeric fluorous copper(II)−carboxylate complex

Abstract : The very fast and efficient water vapor absorption of the dimeric fluorous copper(II)-carboxylate complex [Cu(2)(C(8)F(17)CO(2))(4)(acetone)(2)] (1) leads, in the solid state, to a dramatic decrease of the exchange magnetic coupling between the copper(II) ions and to a drastic change of its powder EPR spectrum.
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Inorganic Chemistry, American Chemical Society, 2009, 48 (13), pp.5623-5625. <10.1021/ic9005218>
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https://hal.archives-ouvertes.fr/hal-00414553
Contributeur : Stéphane Toulin <>
Soumis le : mercredi 9 septembre 2009 - 12:55:06
Dernière modification le : samedi 5 décembre 2015 - 01:51:09

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Artur Motreff, Rosenildo Correa da Costa, Hassan Allouchi, Mathieu Duttine, Corine Mathonière, et al.. Dramatic solid-state humidity-induced modification of the magnetic coupling in a dimeric fluorous copper(II)−carboxylate complex. Inorganic Chemistry, American Chemical Society, 2009, 48 (13), pp.5623-5625. <10.1021/ic9005218>. <hal-00414553>

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