IASI measurements of reactive trace species in biomass burning plumes

Pierre-François Coheur (1) , Lieven Clarisse (1) , Solène Turquety (2) , Daniel Hurtmans (1) , Cathy Clerbaux (1, 2)

1 Spectroscopie de l'atmosphère, Service de Chimie Quantique et Photophysique
2 TROPO - LATMOS

This work presents observations of a series of short-lived species in biomass burning plumes from the Infrared Atmospheric Sounding Interferometer (IASI), launched onboard the MetOp-A platform in October 2006. The strong fires that have occurred in the Mediterranean Basin – and particularly Greece – in August 2007, and those in Southern Siberia and Eastern Mongolia in the early spring of 2008 are selected to support the analyses. We show that the IASI infrared spectra in these fire plumes contain distinctive signatures of ammonia (NH₃), ethene (C₂H₄), methanol (CH₃OH) and formic acid (HCOOH) in the atmospheric window between 800 and 1200 cm⁻¹, with some noticeable differences between the plumes. Peroxyacetyl nitrate (CH₃COOONO₂, abbreviated as PAN) was also observed with good confidence in some plumes and a tentative assignment of a broadband absorption spectral feature to acetic acid (CH₃COOH) is made. For several of these species these are the first reported measurements made from space in nadir geometry. The IASI measurements are analyzed for plume height and concentration distributions of NH₃, C₂H₄ and CH₃OH. The Greek fires are studied in greater detail for the days associated with the largest emissions. In addition to providing information on the spatial extent of the plume, the IASI retrievals allow an estimate of the total mass emissions for NH₃, C₂H₄ and CH₃OH. Enhancement ratios are calculated for the latter relative to carbon monoxide (CO), giving insight in the chemical processes occurring during the transport, the first day after the emission.

Domaines: Biodiversité et Ecologie; Physique Atmosphérique et Océanique [physics.ao-ph]; Planète et Univers [physics]

Pierre-François Coheur, Lieven Clarisse, Solène Turquety, Daniel Hurtmans, Cathy Clerbaux. IASI measurements of reactive trace species in biomass burning plumes. Atmospheric Chemistry and Physics, 2009, 9 (15), pp.5655-5667. ⟨10.5194/acp-9-5655-2009⟩. ⟨hal-00409704⟩