A One-Pot Synthesis of a 243-Allyl Dendrimer under Ambient Conditions

Abstract : Hydrosilylation of a nonaallyl dendritic core using HSi(Me)2Cl followed by reaction with a phenolate dendronic brick bearing three allyl groups, followed by repetition of this sequence of reactions twice, allows a one-pot synthesis of a 243-allyl dendrimer under ambient conditions.
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https://hal.archives-ouvertes.fr/hal-00399008
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Submitted on : Thursday, June 25, 2009 - 2:30:04 PM
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Catia Ornelas, Jaime Ruiz Aranzaes, Eric Cloutet, Didier Astruc. A One-Pot Synthesis of a 243-Allyl Dendrimer under Ambient Conditions. Organic Letters, American Chemical Society, 2006, 8 (13), pp.2751-2753. ⟨10.1021/ol060811t⟩. ⟨hal-00399008⟩

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