A new crosslinkable system based on thermal Huisgen reaction to enhance the stability of electro-optic polymers

Annabelle Scarpaci (1) , Errol Blart (1) , V. Montembault (2) , Laurent Fontaine (2) , Vincent Rodriguez (3) , Fabrice Odobel (1)

1 CEISAM - Chimie Et Interdisciplinarité : Synthèse, Analyse, Modélisation
2 UCO2M - Unité de chimie organique moléculaire et macromoléculaire
3 ISM - Institut des Sciences Moléculaires

The thermal Huisgen cycloaddition reaction is a new and efficient process to crosslink electro-optic polymers, since it leads to an effective increase of the thermal alignment stability of the NLO chromophores.

Domaines: Polymères

Annabelle Scarpaci, Errol Blart, V. Montembault, Laurent Fontaine, Vincent Rodriguez, et al.. A new crosslinkable system based on thermal Huisgen reaction to enhance the stability of electro-optic polymers. Chemical Communications, 2009, 14, pp.1825-1827. ⟨10.1039/B900669A⟩. ⟨hal-00371124⟩