Synthesis of silicated hydroxyapatite Ca10(PO4)6x(SiO4)x(OH)2x

Mickael Palard (1) , T.J. Champion (1) , Sylvie Foucaud (2)

1 SPCTS - Science des Procédés Céramiques et de Traitements de Surface
2 Axe 1 : procédés céramiques

The preparation of silicated hydroxyapatite Ca10(PO4)6x(SiO4)x(OH)2x (SiHA) with 0pxp2 was investigated using a wet precipitation method followed by a heat treatment. X-ray diffraction and Rietveld refinement, Fourier transformed IR (FTIR) spectroscopy, elemental analyses, transmission electron microscopy and thermal analyses were used to characterize the samples. The raw materials were composed of a partially silicated and carbonated apatite and a secondary minor phase containing the excess silicon. Single phase silicated hydroxyapatites, with 0pxp1, could be synthesized after a thermal treatment of the raw powders above 700 1C. The presence of carbonate groups in the raw apatite played an important role in the incorporation of silicates during heating. From the different results, the mechanisms of formation of SiHA are discussed.

Mots clés: Powder synthesis; Silicated hydroxyapatite; Mechanisms of formation

Mickael Palard, T.J. Champion, Sylvie Foucaud. Synthesis of silicated hydroxyapatite Ca10(PO4)6x(SiO4)x(OH)2x. Journal of Solid State Chemistry, 2008, 181, pp.1950-1960. ⟨10.1016/j.jssc.2008.04.027⟩. ⟨hal-00356929⟩