Coalescence of polymer droplets: experiments on collision

Claude Verdier (1)

1 LR - Laboratoire de rhéologie

The coalescence of polymer droplets is a fundamental phenomenon which appears for example when mixing two polymers. When two polymeric droplets collide, a transient regime appears, which results from a competition between interfacial and viscoelastic effects : the spherical droplets deform to give birth to a new drop in a short time (tc) and the drop shape stabilizes after a long time. A novel method is proposed to study experimentally under a microscope the collision between two droplets of one polymer in another one, with different viscosity ratios. This allows to determine the characteristic time tc which defines this phenomenon. The experiments actually show that tc varies like the geometric mean of the viscosities of the two polymers, for the case of a polydimethylsiloxane/polyisobutylene system.

Mots clés: coalescence; droplets

Domaines: Biomécanique [physics.med-ph]; Biomécanique [physics.med-ph]; Mécanique des fluides [physics.class-ph]; Mécanique des fluides [physics.class-ph]

Claude Verdier. Coalescence of polymer droplets: experiments on collision. Comptes Rendus de l'Academie des Sciences. Série IV, Physique, Astronomie, 1999, 1, pp.119-126. ⟨hal-00321757⟩