Oxidation of arylamidoximes by hydrogen peroxide and horseradish peroxidase in water: Easy preparation and X-ray structure of O-(arylimidoyl)arylamidoximes.

Jl Boucher (1) , S. Vadon (1) , A. P. Tomas (1) , B. Viossat (1) , Xxxx Mansuyd (1)

1 IBCP - Institut de biologie et chimie des protéines [Lyon]

The oxidation of arylamidoximes X-C6H4C(NH2)=N-OH (X = H, Me, Cl, NO2, MeO) by H2O2 in the presence of horseradish peroxidase under mild conditions (phosphate buffer pH 7.4, room temperature) yields the corresponding O-(arylimidoyl)arylamidoximes in 30-70% yields. The structure of one of them is established by an X-ray analysis. Copyright (C) 1996 Elsevier Science LtdThe oxidation of arylamidoximes X-C6H4C(NH2)=N-OH (X = H, Me, Cl, NO2, MeO) by H2O2 in the presence of horseradish peroxidase under mild conditions (phosphate buffer pH 7.4, room temperature) yields the corresponding O-(arylimidoyl)arylamidoximes in 30-70% yields. The structure of one of them is established by an X-ray analysis. Copyright (C) 1996 Elsevier Science Ltd

Domaines: Biochimie, Biologie Moléculaire

Jl Boucher, S. Vadon, A. P. Tomas, B. Viossat, Xxxx Mansuyd. Oxidation of arylamidoximes by hydrogen peroxide and horseradish peroxidase in water: Easy preparation and X-ray structure of O-(arylimidoyl)arylamidoximes.. Tetrahedron Letters, 1996, 37, pp.3113-3116. ⟨hal-00315240⟩