PAHs and Organic Matter Partitioning and Mass Transfer from Coal Tar Particles to Water

M. Sardin (1) , M.-O. Simonnot (1) , K. Benhabib (1)

1 LSGC - Laboratoire des Sciences du Génie Chimique

manufactured gas plants and coking plants acts as a longterm source of PAHs. Organic carbon and PAH transfer from coal tar particles to water was investigated with closedlooped laboratory column experiments run at various particle sizes and temperatures. Two models were derived. The first one represented the extraction process at equilibrium and was based on a linear partitioning of TOC and PAHs between coal tar and water. The partition coefficient was derived as well as the mass of extractable organic matter in the particles. The second model dealt with mass transfer. Particle diffusion was the limiting step; organic matter diffusivity in the coal tar was then computed in the different conditions. A good consistency was obtained between experimental and computed results. Hence, the modeling of PAH migration in contaminated soils at the field scale requires taking into account coal tar as the source-term for PAH release

Domaines: Génie des procédés

M. Sardin, M.-O. Simonnot, K. Benhabib. PAHs and Organic Matter Partitioning and Mass Transfer from Coal Tar Particles to Water. Environmental Science and Technology, 2006, 40 (19), pp.6038-6043. ⟨10.1021/es0600431⟩. ⟨hal-00284074⟩