DTA, FTIR and impedance spectroscopy studies on lithium–iron–phosphate glasses with olivine-like local structure

P. Jozwiak (1) , J.E. Garbarczyk (1) , M. Wasiucionek (1) , I. Gorzkowska (2) , F. Gendron (3) , A. Mauger (4) , C.M. Julien (3)

1 Faculty of Physics
2 Faculty of Chemistry
3 INSP - Institut des Nanosciences de Paris
4 IMPMC - Institut de minéralogie et de physique des milieux condensés

Amorphous analogs of lithium–iron–phosphates (LFP) with olivine-like local order were prepared by standard press-quenching method and their thermal stabilities as well as structural and electric properties were studied for the first time. Glass transition temperature Tg determined by DTA method is equal to 492–523 °C depending on the glass composition. Fourier transform infrared (FTIR) absorption spectroscopy was used to study local order. Local structure and thermal properties are almost independent on the lithium content. Electrical properties were studied by impedance spectroscopy. Impedance measurements indicated that the studied lithium–iron–phosphate glasses with olivine-like local order exhibit predominantly electronic (polaronic) conductivity. Total electrical conductivity at 450 °C for a glass of nominal composition LiFePO4 approaches 10− 2 S/cm. Electrical conductivity at 25 °C of Li0.4FePO4 glass after nanocrystallization (caused by heating up from room temperature to the beginning of crystallization temperature) increased by a factor close to 4. Nanocrystallization seems to be the way for electrical conductivity improvement of olivine-like cathode materials.

Mots clés: Phospho-olivines; Lithium–iron–phosphate glasses; Cathode materials; Li-ion batteries; Nanocrystallization; DTA; FTIR

Domaines: Autre [cond-mat.other]

P. Jozwiak, J.E. Garbarczyk, M. Wasiucionek, I. Gorzkowska, F. Gendron, et al.. DTA, FTIR and impedance spectroscopy studies on lithium–iron–phosphate glasses with olivine-like local structure. Solid State Ionics, 2008, 179, pp.46-50. ⟨10.1016/j.ssi.2007.12.024⟩. ⟨hal-00282497⟩