Fluorescence patterning through photoinduced migration of squaraine-functionalized azo derivatives

Li-Hong Liu (1, 2) , Keitaro Nakatani (1, 2) , Robert Bernard Pansu (1, 2) , Jean-Jacques Vachon (1, 2) , Patrick Tauc (2, 3) , Eléna Ishow (1, 2)

1 PPSM - Laboratoire de Photophysique et Photochimie Supramoléculaires et Macromoléculaires
2 IDA - Institut d'Alembert
3 LBPA - Laboratoire de Biologie et de Pharmacologie Appliquée

New photochromic and fluorescent dyes are formed by covalently attaching emissive squaraine units to azo moieties. Illumination of doped matrices by light interference fringes provokes the reversible migration of the dyes and the formation of fluorescent gratings, as shown schematically in the figure. The visualization of the gratings is performed by using fluorescence confocal microscopy.

Mots clés: SURFACE-RELIEF GRATINGS; ELECTRON-TRANSFER; DYES; CHEMISTRY; PHOTOPHYSICS; AZOBENZENE; MECHANISM; EMISSION; POLYMERS

Domaines: Chimie théorique et/ou physique; Matériaux

Li-Hong Liu, Keitaro Nakatani, Robert Bernard Pansu, Jean-Jacques Vachon, Patrick Tauc, et al.. Fluorescence patterning through photoinduced migration of squaraine-functionalized azo derivatives. Advanced Materials, 2007, 19 (3), pp.433-436. ⟨10.1002/adma.200601695⟩. ⟨hal-00169021⟩