Approximate radiative properties of methane at high temperature

Marie-Yvonne Perrin (1) , Anouar Soufiani (1)

1 EM2C - Laboratoire d'Énergétique Moléculaire et Macroscopique, Combustion

Band model parameters for high-temperature methane have been generated up to 2000 K from an extended spectroscopic database. Part of the spectroscopic data are issued from calculations made in the framework of the effective Hamiltonian approach. These data have been completed by a statistical extrapolation. The calculations of global radiative properties such as band absorbtances and total emissivities are in good agreement with the available experimental data showing that the contribution of the hot bands is correctly taken into account. Finally, the degree of correlation between CH4, CO2 and H2O spectra in typical conditions of combustion applications is discussed. Band model parameters are available upon request.

Mots clés: methane; radiative properties; high temperature; band model parameters

Marie-Yvonne Perrin, Anouar Soufiani. Approximate radiative properties of methane at high temperature. Journal of Quantitative Spectroscopy and Radiative Transfer, 2007, 103 (1), pp.3-13. ⟨10.1016/j.jqsrt.2006.07.018⟩. ⟨hal-00259948⟩