Functionalisation of the framework of mesoporous organosilicas by rare-earth complexes

Ahmad Mehdi (1) , Robert Corriu (1) , Eric Besson (1) , Catherine Reyé (1)

1 ICGM ICMMM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier

A mesoporous hybrid material containing free phosphine oxide ligands in the pore walls was prepared in the presence of a structure-directing agent. The phosphine oxide ligands were proved to operate as templates for further erbium(III) and/or ytterbium(III) ion complexation.

Domaines: Matériaux

Ahmad Mehdi, Robert Corriu, Eric Besson, Catherine Reyé. Functionalisation of the framework of mesoporous organosilicas by rare-earth complexes. Journal of Materials Chemistry, 2005, 16, pp.246. ⟨10.1039/b514878b⟩. ⟨hal-00186060⟩