Double filling in skutterudites: a promising path to improved thermoelectric properties

Eric Alleno (1) , David Bérardan (1) , Claude Godart (1) , M. Puyet (2) , B. Lenoir (2) , R. Lackner (3) , E. Bauer (3) , Luc Girard (4) , Didier Ravot (4)

1 ICMPE - Institut de Chimie et des Matériaux Paris-Est
2 LPM - Laboratoire de physique des matériaux
3 Institute of Solid State Physics
4 ICGM ICMMM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier

We have investigated the thermoelectric properties of the Ce0.9_yYbyFe4Sb12 series as well as those of a few compounds in the series Cey/2Yby/2Fe4_xCoxSb12. In the former series, increasing the Yb fraction decreases the resistivity and the Seebeck coefficient. These effects are related to the fact that Yb is not trivalent in this series. In Ce0.40Yb0.53Fe4Sb12, the phonon part of the thermal conductivity is strongly reduced compared to Ce0.85Fe4Sb12, leading to a larger figure of merit. We think that the increase of the mass and bonding fluctuations on the rare-earth site would be the main reason for this reduction. In the latter series, an extrapolated value of ZT = 0:95 at 800K was obtained in not yet optimized Ce0.44Yb0.32Fe3.02Co0.98Sb12.

Mots clés: skutterudites; Seebeck coefficient; electrical resistivity; thermal conductivity; thermoelectricity

Domaines: Science des matériaux [cond-mat.mtrl-sci]

Eric Alleno, David Bérardan, Claude Godart, M. Puyet, B. Lenoir, et al.. Double filling in skutterudites: a promising path to improved thermoelectric properties. Physica B: Condensed Matter, 2006, 383, pp.103-106. ⟨10.1016/j.physb.2006.03.068⟩. ⟨hal-00182691⟩