Anionic ring-opening polymerization of var epsilon-caprolactone in supercritical carbon dioxide: parameters influencing the reactivity

Vincent Bergeot (1, 2) , Thierry Tassaing (3) , Marcel Besnard (3) , François Cansell (1) , Anne-Françoise Mingotaud (4)

1 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux
2 LCPO - Laboratoire de Chimie des polymères organiques
3 LPCM - Laboratoire de Physico-Chimie Moléculaire
4 IMRCP - Interactions moléculaires et réactivité chimique et photochimique

The anionic ring-opening polymerization of var epsilon-caprolactone in supercritical CO2 is described using different metal alkoxides as initiators...

Mots clés: Polymerization; Phase diagrams; IR spectroscopy; Supercritical carbon dioxide

Domaines: Matériaux

Vincent Bergeot, Thierry Tassaing, Marcel Besnard, François Cansell, Anne-Françoise Mingotaud. Anionic ring-opening polymerization of var epsilon-caprolactone in supercritical carbon dioxide: parameters influencing the reactivity. Journal of Supercritical Fluids, 2004, 28 (2-3), pp.249-261. ⟨10.1016/S0896-8446(03)00040-8⟩. ⟨hal-00137312⟩