A stable hydrido amido ruthenium complex bearing a tridentate iminophosphorane-phosphine-amine ligand.

Leila Boubekeur (1) , Nicolas Mézailles (1) , Louis Ricard (1) , Pascal Le Floch (1)

1 DCPH - Laboratoire Hétéroéléments et Coordination

A heterotridentate (P,N,N') ligand featuring phosphine, iminophosphorane, and amine groups has been prepared in high yield. The corresponding dichlororuthenium(II) complex reacts with base in 2-propanol to give a stable hydrido amido complex. The lack of hydrogens that are to the amine allowed for the isolation and structural characterization of this hydrido amido species by X-ray diffraction.

Domaines: Chimie de coordination

Leila Boubekeur, Nicolas Mézailles, Louis Ricard, Pascal Le Floch. A stable hydrido amido ruthenium complex bearing a tridentate iminophosphorane-phosphine-amine ligand.. Organometallics, 2006, 25, pp.315. ⟨10.1021/om050738v⟩. ⟨hal-00090555⟩