Hybrid bidentate ligand for functional recognition: an application to regioselective C=C double bond hydrogenation

Frédéric Goettmann (1) , Pascal Le Floch (2) , Clément Sanchez (1)

1 LCMCP (site Paris VI) - Laboratoire de Chimie de la Matière Condensée de Paris (site Paris VI)
2 DCPH - Laboratoire Hétéroéléments et Coordination

Regioselectivity increases in C=C double bond hydrogenation could be obtained for Lewis basic substrates on a Lewis acidic support by using a rhodium complex supported on a mesoporous solid.

Mots clés: catalyzed-asymmetric-1; 4-addition; homogeneous-catalysis; artificial-enzymes; arylboronic-acids

Domaines: Chimie de coordination

Frédéric Goettmann, Pascal Le Floch, Clément Sanchez. Hybrid bidentate ligand for functional recognition: an application to regioselective C=C double bond hydrogenation. Chemical Communications, 2006, -, pp.2036. ⟨10.1039/b600127k⟩. ⟨hal-00090503⟩