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Article Dans Une Revue Journal of electroanalytical chemistry and interfacial electrochemistry Année : 2007

On the small-scale statistics of turbulent mixing in electrochemical systems

Résumé

Using the electrochemical method, measurements were made in a plane channel liquid flow, for which the Reynolds number (Re=U*a/v is the mean velocity and a is the hydraulic diameter) is variable between 3000 and 40,000. The Schmidt number of the salt (here, ferri-ferrocyanide) diffusing in water is typically about 1400, consequently the diffusion layer is located inside the viscous sublayer (y+ <0.5, where superscripts + denote quantities dimensionless with respect to wall variables). The scalar field fluctuations are maintained by a mean concentration gradient, imbedded in a strongly sheared velocity field. The skewness and flatness factors were used to investigate the concentration field in the near-vicinity of the wall (in terms of anisotropy and internal intermittency). Thus, the concentration PDFs are very nearly Gaussian, with a slight dissymmetry that dimishes with increasing Reynolds numbers. on the directionx parallel to the wall, the skevness factor of deltae/deltax is about 1, indepently on the Reynold number . The property is very similar to that of a Pr~1 passive scalar mixing in a sheared flow, already studied in the literature.

Dates et versions

hal-00086785 , version 1 (19-07-2006)

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Xavier Adolphe, Luminita Danaila, Sergueï Martemianov. On the small-scale statistics of turbulent mixing in electrochemical systems. Journal of electroanalytical chemistry and interfacial electrochemistry, 2007, pp.00000. ⟨10.1016/j.jelechem.2006.04.023⟩. ⟨hal-00086785⟩
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