Electron density distribution of an oxamato bridged Mn(II)-Cu(II) bimetallic chain, correlation to magnetic properties.

Sébastien Pillet (1) , Mohamed Souhassou (1) , Corine Mathonière (1) , Claude Lecomte (1)

1 CRM2 - Cristallographie, Résonance Magnétique et Modélisations

The electron density distribution of the ferrimagnetic MnCu(pba)(H2O)3·2H2O chain compound, where pba stands for 1,3-propylenebis(oxamato), has been derived from high resolution X-ray diffraction measurements at 114 K using a multipolar model...

Mots clés: Electron density; Crystal structure; Electron configuration; Electron delocalization; Hydrogen bond; X-ray diffraction; Exchange interaction; Manganese

Domaines: Matériaux

Sébastien Pillet, Mohamed Souhassou, Corine Mathonière, Claude Lecomte. Electron density distribution of an oxamato bridged Mn(II)-Cu(II) bimetallic chain, correlation to magnetic properties.. Journal of the American Chemical Society, 2004, 126, pp.1219-1228. ⟨10.1021/ja030279u⟩. ⟨hal-00016224⟩