A differential method for bounding the ground state energy

Amaury Mouchet (1)

1 LMPT - Laboratoire de Mathématiques et Physique Théorique

For a wide class of Hamiltonians, a novel method to obtain lower and upper bounds for the lowest energy is presented. Unlike perturbative or variational techniques, this method does not involve the computation of any integral (a normalisation factor or a matrix element). It just requires the determination of the absolute minimum and maximum in the whole configuration space of the local energy associated with a normalisable trial function (the calculation of the norm is not needed). After a general introduction, the method is applied to three non-integrable systems: the asymmetric annular billiard, the many-body spinless Coulombian problem, the hydrogen atom in a constant and uniform magnetic field. Being more sensitive than the variational methods to any local perturbation of the trial function, this method can used to systematically improve the energy bounds with a local skilled analysis; an algorithm relying on this method can therefore be constructed and an explicit example for a one-dimensional problem is given.

Mots clés: differential method; Barta's inequalities; ground state

Domaines: Physique Quantique [quant-ph]; Dynamique Chaotique [nlin.CD]; Théorie spectrale [math.SP]

Amaury Mouchet. A differential method for bounding the ground state energy. Journal of Physics A: Mathematical and Theoretical, 2005, 38, pp.1039. ⟨hal-00003589⟩