Organic Electrochemical Transistors Based on PEDOT with Different Anionic Polyelectrolyte Dopants

Sahika Inal 1 Jonathan Rivnay 1 Anna I. Hofmann 2 Ilke Uguz 1 Muhammad Mumtaz 2, 3 Dimitrios Katsigiannopoulos 2 Cyril Brochon 2, 3 Eric Cloutet 2, 3 Georges Hadziioannou 2, 3 George G. Malliaras 1
1 Ecole Natl Super Mines, Dept Bioelect
2 LCPO - Laboratoire de Chimie des Polymères Organiques
3 TEAM 4 LCPO
Abstract : Recent applications of organic electrochemical transistors (OECTs) in bioelectronics motivate the search for new materials with mixed electronic and ionic conductivity. We investigate the characteristics of a series of poly(3,4-ethylene-dioxythiophene) (PEDOT)-based materials with a new class of anionic polyelectrolytes used as dopants and stabilizers, replacing the traditionally used poly(styrene sulfonate) (PSS). We show that the backbone of the polyanion plays a major role in determining device performance, while its molecular weight and the counter ion used during PEDOT synthesis play a less important role. We find that transconductance increases with the degree of swelling of the film, consistent with enhanced ion transport. Finally, we identify a polymer that offers performance close to the state-of-the-art. This work highlights the importance of the polyanion phase as a means to control OECT performance.
Keywords : 4-ETHYLENEDIOXYTHIOPHENE)/POLY(4-STYRENE-SULFONATE) BIOELECTRONICS electrochemical mixed conductivity PEDOT:PSS polyanion transistor CONDUCTING POLYMERS TRANSCONDUCTANCE FILMS POLY(3 ELECTRODES SOLVENTS
Type de document :
Article dans une revue
Journal of Polymer Science Part B: Polymer Physics, Wiley, 2016, 54 (2), pp.147-151, SI. 〈10.1002/polb.23938 〉
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https://hal.archives-ouvertes.fr/hal-01369641
Contributeur : Dominique Richard <>
Soumis le : mercredi 21 septembre 2016 - 12:14:36
Dernière modification le : jeudi 11 janvier 2018 - 06:28:09

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Sahika Inal, Jonathan Rivnay, Anna I. Hofmann, Ilke Uguz, Muhammad Mumtaz, et al.. Organic Electrochemical Transistors Based on PEDOT with Different Anionic Polyelectrolyte Dopants . Journal of Polymer Science Part B: Polymer Physics, Wiley, 2016, 54 (2), pp.147-151, SI. 〈10.1002/polb.23938 〉. 〈hal-01369641〉

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