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Article Dans Une Revue Chemical Reviews Année : 2017

Bicomponent Supramolecular Architectures at the Vacuum–Solid Interface

Xavier Bouju
André Gourdon

Résumé

This review aims at giving the readers the basic concepts needed to understand two-dimensional bimolecular organizations at the vacuum–solid interface. The first part describes and analyzes molecules–molecules and molecules–substrates interactions. The current limitations and needs in the understanding of these forces are also detailed. Then, a critical analysis of the past and recent advances in the field is presented by discussing most of the key papers describing bicomponents self-assembly on solid surface in an ultrahigh vacuum environment. These sections are organized by considering decreasing molecule–molecule interaction strengths (i.e. starting from strong directional multiple H bonds up to weaker nondirectional bonds taking into account the increasing fundamental role played by the surface). Finally, we conclude with some research directions (predicting self-assembly, multi-components systems, and nonmetallic surfaces) and potential applications (porous networks and organic surfaces).

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Autre
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Dates et versions

hal-01737665 , version 1 (19-03-2018)

Identifiants

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Xavier Bouju, Cristina Mattioli, Grégory Franc, Adeline Pujol, André Gourdon. Bicomponent Supramolecular Architectures at the Vacuum–Solid Interface. Chemical Reviews, 2017, 117 (3), pp.1407-1444. ⟨10.1021/acs.chemrev.6b00389⟩. ⟨hal-01737665⟩
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