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Towards a complete macroscopic modelling of the thermo-chemomechanical behaviour of MIECs
Valentin O., Blond E., Richet N.
in Proceeding of 12th ECerS - 12th Conference of European Ceramic Society, Stockholm : Sweden (2011) - http://hal.archives-ouvertes.fr/hal-00611383
Communications avec actes
Sciences de l'ingénieur/Mécanique/Mécanique des matériaux
Physique/Mécanique/Mécanique des matériaux
Towards a complete macroscopic modelling of the thermo-chemomechanical behaviour of MIECs
Olivier Valentin 1, Eric Blond () 1, Nicolas Richet 2
1 :  Laboratoire PRISME (PRISME)
Université d'Orléans : EA4229 – ENSI Bourges
8, rue Léonard de Vinci 45072 Orléans Cédex 2
France
2 :  Air Liquide / Centre de Recherche Claude Delorme [Jouy-en-Josas] (CRCD)
Air Liquide
chemin de la porte des Loges Les loges en Josas BP 126 78 354 Jouy-en-Josas
France
This paper proposes a macroscopic model of the thermo-chemo-mechanical behaviour of MIECs dedicated to mechanical engineering. Developed within the framework of phenomenological approach, the state variables of the model are the oxygen partial pressure, the temperature and the total strain. Oxygen bulk diffusion is describes by the local Onsager approach and surface exchange are modelled by the use of a mass Biot number. Not only focus on the semi-permeation induced strain, the proposed model also included the effect of the temperature. Strain predicted by a model based on defect equilibrium and strain predicted by the macroscopic approach are in good agreement as it is illustrates on the particular case of La0.8Sr0.2Fe0.7Ga0.3O3-δ. The implementation of the model in the F.E.A code Abaqus allows the exploration of the evolution of the stress state during the membrane life, from sealing stage to reactor exploitation.
Anglais
20/06/2011

Proceeding of 12th ECerS
internationale
19/06/2011
Oral 214

12th Conference of European Ceramic Society
19/06/2011
23/06/2011
Stockholm
Suède

MIECs – Chemical expansion – Thermo-chemo-mechanical behaviour
MMH

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