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Université d'Orléans |  |
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Université d'Orléans | |
| HAL : hal-00267392, version 1 |
| Fiche détaillée |  Récupérer au format |
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| Concepts in Magnetic Resonance Part A (2008) in press |
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| Two and Three-dimensional Through-Bond Homonuclear-Heteronuclear Correlation Experiments for Quadrupolar Nuclei in Solid-State NMR Applied to 27Al-O-31P-O-27Al networks |
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| M. Deschamps 1, 2D. Massiot 1, 2 |
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| ANR RMNHRHC Collaboration(s) |
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| (2008) |
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| Through-bond correlation experiments can be realised in solids between spins of type X, separated by four chemical bonds, in X-O-Y-O-X molecular motives, provided a scalar coupling (J) between X and Y exists. In the 2D-Homonuclear-Heteronuclear Single Quantum Correlation (H-HSQC) experiment presented here, the central transitions of quadrupolar 27Al spins can be correlated via the scalar coupling J2 between 27Al (X) and 31P (Y) in materials featuring Al-O-P-O-Al motives. A 3D homonuclear/heteronuclear correlation experiment can also be performed, providing the correlation map characterizing the two 27Al and the 31P NMR signatures of 27Al-O-31P-O-27Al chemically bonded molecular motifs. |
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| 1 : | Fédération RMN du Solide à Hauts Champs (FRMN-SHC) |
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CNRS : FR2950 – Université d'Orléans |
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| 2 : | Conditions Extrêmes et Matériaux : Haute Température et Irradiation (CEMHTI) |
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CNRS : UPR3079 – Université d'Orléans |
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| Domaine | : | Chimie/Matériaux |
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| Liste des fichiers attachés à ce document : | |||||
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| hal-00267392, version 1 | |
| http://hal.archives-ouvertes.fr/hal-00267392 | |
| oai:hal.archives-ouvertes.fr:hal-00267392 | |
| Contributeur : Dominique Massiot | |
| Soumis le : Jeudi 27 Mars 2008, 13:20:42 | |
| Dernière modification le : Jeudi 27 Mars 2008, 13:40:43 | |
