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E-MRS IUMRS ICEM 2006 Spring Meeting - Symposium U: Si-based Materials for Advanced Microelectronic Devices: Synthesis, Defects and Diffusion, Nice : France
Structural and nuclear characterizations of defects created by noble gas implantation in silicon oxide
H. Assaf 1, E. Ntsoenzok 1, 2, M.-F. Barthe 1, M.-O. Ruault 3, T. Sauvage 1, S. Ashok 4
(2006)

Thermally grown silicon oxide layer was implanted at room temperature with 300keV Xe at fluences ranging from 0.5 to 5x10$^16$Xe/cm$^2$. Bubbles created after Xe-implantation provided a low-k silicon oxide that has potential use as a dielectric material for interconnects in Si integrated circuits. Transmission Electron Microscopy (TEM), Rutherford Backscattering Spectrometry (RBS) and Positron Annihilation Spectroscopy (PAS) were used to provide a comprehensive characterization of defects (bubbles, vacancy, gas atoms and other types of defects) created by Xe implantation in $SiO_2$ layer. These measurements suggest that the bubbles observed with TEM for all fluences were a consequence of the interaction between Xe and vacancies (V), with $V_nXe_m$ complexes created in the zone where V and Xe profiles overlap. Negatively charged defects such as ($Si-O^-$, $Si-O-O^-$ and $O_2^-$) are also created after implantation.
1:  Centre d'Études et de Recherches par Irradiation (CERI)
CNRS : UPR33
2:  Laboratoire d' Électronique, Signaux, Images (LESI)
Université d'Orléans – Institut Universitaire de Technologie de Chartres – Ecole Polytechnique de l'Université d'Orléans
3:  Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM)
CNRS : UMR8609 – IN2P3 – Université Paris XI - Paris Sud
4:  Department of Engineering Science (DEPARTMENT OF ENGINEERING SCIENCE)
The Pennsylvania State University
Chemical Sciences/Cristallography

Physics/Condensed Matter/Other
Low-k SiO2 – Defects – Bubbles – Xe implantation – Positron annihilation spectroscopy – Rutherford Backscattering – Transmission electron microscopy
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