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Raman studies of corrosion layers formed on archaeological irons in various media
Bellot-Gurlet L., Neff D., Reguer S., Monnier J., Saheb M., Dillmann P.
Journal of Nano Research 8 (2009) 147-156 - http://hal.archives-ouvertes.fr/hal-00477440
Article in peer-reviewed journal
Chemical Sciences/Analytical chemistry
Chemical Sciences/Material chemistry
Chemical Sciences/Inorganic chemistry
Engineering Sciences/Materials
Humanities and Social Sciences/Cultural heritage and museology
Sciences of the Universe/Earth Sciences/Mineralogy
Raman studies of corrosion layers formed on archaeological irons in various media
Ludovic Bellot-Gurlet () 1, Delphine Neff () 2, Solenn Reguer () 3, Judith Monnier () 4, Mandana Saheb 2, Philippe Dillmann 2, 5
1:  Laboratoire de Dynamique Interactions et Réactivité (LADIR)
http://www.ladir.cnrs.fr/
CNRS : UMR7075 – Université Pierre et Marie Curie [UPMC] - Paris VI
Bât. F - Esc. 74 - 3ème étage 4, place Jussieu 75005 PARIS
France
2:  Laboratoire Pierre Süe (LPS)
http://www-drecam.cea.fr/lps/index.html
CNRS : UMR9956 – CEA : DSM/IRAMIS
bât. 637 et bât. 639 CE Saclay 91191 GIF SUR YVETTE CEDEX
France
3:  Division Expériences - DIFFABS Synchrotron Soleil (Synchrotron Soleil)
SOLEIL
L'Orme des Merisiers, Saint-Aubin - BP 48, 91192 Gif sur Yvette Cedex, France
France
4:  Institut de Chimie et des Matériaux Paris-Est (ICMPE)
CNRS : UMR7182 – Université Paris-Est Créteil Val-de-Marne (UPEC)
2 à 8 rue Henri Dunant 94320 THIAIS
France
5:  Institut de Recherches sur les Archéomatériaux (IRAMAT)
CNRS : UMR5060 – Université de Technologie de Belfort-Montbeliard – Université Michel de Montaigne - Bordeaux III – Université d'Orléans
France
The description and identification of corrosion products formed on archaeological iron artefacts need various approaches at different observation scales. Among analytical techniques available to document phase structure at the microscopic range, Raman spectroscopy offers sensitivity and discrimination between iron corrosion products with an easy implementation. Results obtained for iron artefacts corrosion in soils and atmosphere are presented. Corrosion forms observed for anoxic and aerated soils on one hand and indoor atmosphere on the other are documented. Beyond the identification and organisation of corrosion products through hyperspectral imaging, Raman micro-spectroscopy could also provide quantitative phase proportions which will be needed in the proposition of reactivity diagnosis indicators.
English
2009

Journal of Nano Research
international
2009
8
147-156

Raman spectroscopy – iron corrosion – ancient artefact – imaging.

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