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Université de Provence - Aix-Marseille I Hyper Articles en Ligne |
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Université de Provence - Aix-Marseille I Hyper Articles en Ligne |
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| HAL : hal-00699834, version 1 |
| DOI : 10.1039/c1cc15242d |
| Fiche détaillée |  Récupérer au format |
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| Chemical Communications 48, 5 (2012) 654-656 |
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| Non-aqueous solvents for DNP surface enhanced NMR spectroscopy |
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| Alexandre Zagdoun 1Aaron J. Rossini 1 |
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| (2012) |
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| A series of non-aqueous solvents combined with the exogenous biradical bTbK are developed for DNP NMR that yield enhancements comparable to the best available water based systems. 1,1,2,2-tetrachloroethane appears to be one of the most promising organic solvents for DNP solid-state NMR. Here this results in a reduction in experimental times by a factor of 1000. These new solvents are demonstrated with the first DNP surface enhanced NMR characterization of an organometallic complex supported on a hydrophobic surface. |
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| 1 : | Institut des Sciences Analytiques (ISA) |
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Université de Lyon – CNRS : UMR5280 – Université Claude Bernard - Lyon I – École Normale Supérieure - Lyon |
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| 2 : | Laboratory for Inorganic |
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Eidgenössische Technische Hochschule Zürich - ETH Zurich |
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| 3 : | Laboratoire de Chimie, Catalyse, Polymères et Procédés, R 5265 (C2P2) |
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CNRS : UMR5265 – CPE LYON – Université Claude Bernard - Lyon I |
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| 4 : | Laboratoire Chimie Provence (LCP) |
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Université de Provence - Aix-Marseille I – CNRS : UMR6264 |
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| 5 : | Bruker BioSpin Corporation |
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Bruker BioSpin Corporation |
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| Centre de RMN à très hauts champs |
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| Domaine | : | Chimie/Chimie analytique |
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| DYNAMIC NUCLEAR-POLARIZATION |
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| hal-00699834, version 1 | |
| http://hal.archives-ouvertes.fr/hal-00699834 | |
| oai:hal.archives-ouvertes.fr:hal-00699834 | |
| Contributeur : Agnès Bussy | |
| Soumis le : Lundi 21 Mai 2012, 16:18:58 | |
| Dernière modification le : Lundi 8 Avril 2013, 13:28:15 | |
