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university of Provence - Aix-Marseille I |  |
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university of Provence - Aix-Marseille I | |
| HAL: hal-00699834, version 1 |
| DOI: 10.1039/c1cc15242d |
| Detailed view |  Export this paper |
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| Chemical Communications 48, 5 (2012) 654-656 |
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| Non-aqueous solvents for DNP surface enhanced NMR spectroscopy |
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| Alexandre Zagdoun 1Aaron J. Rossini 1 |
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| (2012) |
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| A series of non-aqueous solvents combined with the exogenous biradical bTbK are developed for DNP NMR that yield enhancements comparable to the best available water based systems. 1,1,2,2-tetrachloroethane appears to be one of the most promising organic solvents for DNP solid-state NMR. Here this results in a reduction in experimental times by a factor of 1000. These new solvents are demonstrated with the first DNP surface enhanced NMR characterization of an organometallic complex supported on a hydrophobic surface. |
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| 1: | Institut des Sciences Analytiques (ISA) |
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Université de Lyon – CNRS : UMR5280 – Université Claude Bernard - Lyon I – École Normale Supérieure - Lyon |
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| 2: | Laboratory for Inorganic |
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Eidgenössische Technische Hochschule Zürich - ETH Zurich |
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| 3: | Laboratoire de Chimie, Catalyse, Polymères et Procédés, R 5265 (C2P2) |
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CNRS : UMR5265 – CPE LYON – Université Claude Bernard - Lyon I |
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| 4: | Laboratoire Chimie Provence (LCP) |
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Université de Provence - Aix-Marseille I – CNRS : UMR6264 |
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| 5: | Bruker BioSpin Corporation |
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Bruker BioSpin Corporation |
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| Centre de RMN à très hauts champs |
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| Subject | : | Chemical Sciences/Analytical chemistry |
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| DYNAMIC NUCLEAR-POLARIZATION |
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| hal-00699834, version 1 | |
| http://hal.archives-ouvertes.fr/hal-00699834 | |
| oai:hal.archives-ouvertes.fr:hal-00699834 | |
| From: Agnès Bussy | |
| Submitted on: Monday, 21 May 2012 16:18:58 | |
| Updated on: Monday, 8 April 2013 13:28:15 | |
