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university of Provence - Aix-Marseille I |  |
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university of Provence - Aix-Marseille I | |
| HAL: hal-00695823, version 1 |
| DOI: 10.1039/c2jm15887f |
| Detailed view |  Export this paper |
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| Journal of Materials Chemistry 22 (2012) 10266 |
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| Effect of the organic functionalization of flexible MOFs on the adsorption of CO2 |
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| Thomas Devic 1Fabrice Salles 2 |
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| (2012) |
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| The adsorption of CO2 by a series of functionalized flexible MIL-53(Fe) solids has been evaluated through a combination of in situ X-ray power diffraction, adsorption calorimetry, IR spectroscopy and computer modelling. It appears that (i) strongly polar groups maintain the nonporous structure in its closed form due to strong intra-framework interactions and (ii) less polar functional groups allow only a modulation of the CO2 -framework interactions, in some cases with a disappearance of the initial intra-framework µ2 -OH/X hydrogen bonds, but do not interact directly with the CO2 molecules. |
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| 1: | INSTITUT LAVOISIER |
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CNRS : UMR8180 – Université de Versailles Saint-Quentin-en-Yvelines |
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| 2: | Institut Charles Gerhardt - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICG ICMMM) |
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CNRS : UMR5253 – Université Montpellier I – Université Montpellier II - Sciences et techniques – Ecole Nationale Supérieure de Chimie de Montpellier |
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| 3: | Laboratoire Chimie Provence (LCP) |
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Université de Provence - Aix-Marseille I – CNRS : UMR6264 |
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| 4: | Laboratoire catalyse et spectrochimie (LCS) |
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CNRS : UMR6506 – Ecole Nationale Supérieure d'Ingénieurs de Caen |
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| 5: | Matériaux divisés, revêtements, électrocéramiques (MADIREL) |
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CNRS : UMR6121 – Université de Provence - Aix-Marseille I |
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| 6: | Institut de la matière condensée et des nanosciences / Institute of Condensed Matter and Nanosciences (IMCN) |
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Université Catholique de Louvain (UCL) - Belgique |
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| Subject | : | Chemical Sciences/Theoretical and/or physical chemistry Engineering Sciences/Materials |
| hal-00695823, version 1 | |
| http://hal.archives-ouvertes.fr/hal-00695823 | |
| oai:hal.archives-ouvertes.fr:hal-00695823 | |
| From: Fabrice Salles | |
| Submitted on: Thursday, 10 May 2012 08:30:40 | |
| Updated on: Thursday, 10 May 2012 08:30:40 | |
