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Dissolved organic matter fluorescence as a water-flow tracer in the tropical wetland of Pantanal of Nhecolandia, Brazil
Mariot M., Dudal Y., Furian S., Sakamoto A., Valles V., Fort M., Barbiero L.
Science of The Total Environment 388, 1-3 (2007) 184-193 - http://hal.ird.fr/ird-00363984
Article in peer-reviewed journal
Life Sciences/Agricultural sciences/Soil study
Dissolved organic matter fluorescence as a water-flow tracer in the tropical wetland of Pantanal of Nhecolandia, Brazil
M. Mariot 1, Y. Dudal 2, S. Furian 3, A. Sakamoto 4, V. Valles 1, M. Fort 5, Laurent Barbiero ( ) 6
1:  Laboratoire d'Hydrogéologie d'Avignon (LHA)
http://www.lha.univ-avignon.fr/
Université d'Avignon : EA2665
33 Rue Louis Pasteur 84000 Avignon
France
2:  Unité mixte de recherche Climat Sol et Environnement (UMR CSE 1114)
Institut national de la recherche agronomique (INRA) – Université d'Avignon
INRA CR AVIGNON Domaine Saint-Paul Site Agroparc 84914 Avignon cedex 9
France
3:  Laboratorio de pedologia (Laboped)
Universidade de São Paulo
Departamento de Geografia Universidade de São Paulo C.P. 8105, 05508-900, São Paulo
Brazil
4:  Laboratório de Pedologia, Departamento de Geografia
Universidade Federal do Mato Grosso do Sul
Campus de Nova Andradina Av. Eurico Soares Andrade 1020 79750-000, Nova Andradina-MS
Brazil
5:  Pole de recherche pour l'organisation et la diffusion de l'information géographique (PRODIG)
http://www.prodig.cnrs.fr/
CNRS : UMR8586 – Université Paris I - Panthéon-Sorbonne – Université Paris IV - Paris Sorbonne – Université Paris VII - Paris Diderot – Ecole Pratique des Hautes Etudes – Institut de recherche pour le développement [IRD] : UR215
PRODIG - 2 rue Valette - 75005 Paris
France
6:  Laboratoire des Mécanismes et Transfert en Géologie (LMTG)
http://www.lmtg.obs-mip.fr/
CNRS : UMR5563 – Observatoire Midi-Pyrénées – Université Paul Sabatier [UPS] - Toulouse III – Institut de recherche pour le développement [IRD] : UMR154
14 avenue Edouard Belin 31400 Toulouse
France
The Nhecolandia is a sub-region of the Brazilian Pantanal wetland, where saline and freshwater lakes coexist in close proximity. Measurements of dissolved organic carbon (DOC) content and analysis of fluorescence excitation-emission matrices (EEM) were conducted in an effort to characterize spatial variability in concentration and source of dissolved organic matter (DOM) and to further understand the hydrochemical functioning of this complex environment. Increasing pH under the influence of evaporation resulted in an increasing DOC solubility ranging from 50 to over 300 mgC L-1 in surface water. Spectrofluorescence characterisation indicates the presence of several families of dissolved organic matter (fulvic and humic-type and proteinaceous materials), which are related to the type of lake and its hydro-bio-geochemical functioning. Moreover, the fluorescence signatures from lake water DOM and from surrounding soil-water-extracted organic matter (WEOM) show strong similarities although some labile proteinaceous compounds disappeared during humification. Results from the characterisation of DOM and WEOM not only suggest that spectrofluorescence is a reliable technique for the tracing of water flows, but also for the marking of the origin of organic horizons in this environment.
English

Science of the Total Environment (Sci. Total Environ.)
Publisher Elsevier
ISSN 0048-9697 
not specified
2007
388
1-3
184-193

spectrofluorecence – organic matter – tracing – alkaline wetland – pantanal – Brazil
Capes-Cofecub 412-03
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