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Journal of Magnetic Resonance 205 (2010) 315-318
Structural properties of 2D NMR relaxation spectra of diffusive systems
Stéphane Rodts ( ) 1, Dimitri Bytchenkoff ( ) 1
(15/05/2010)

Much has been learnt and speculated about the form of 2D NMR relaxation spectra of diffusive systems. Herein we show that the eigen-modes formalism can help to establish a number of fundamental structural properties, i.e. symmetries, overall intensities, signs and relative intensities of the diagonal and cross components, of such spectra, on which one can safely rely in analysing experimental data. More specifically, we prove that the correlation T1–T2 spectra will always have negative peaks, thus making questionable the nowadays wide spread strategy in developing inverse Laplace transformation algorithms.
1 :  Laboratoire Navier
Ecole des Ponts ParisTech – CNRS : UMR8205 – IFSTTAR
Milieux poreux
Physique/Physique/Chimie-Physique

Physique/Physique/Physique Générale

Physique/Matière Condensée/Science des matériaux

Physique/Physique/Physique Numérique
Relaxation – Diffusion – Porous – Laplace