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Molecular Physics 102 (2004) 1221
On the use of the group SO(4,2) in atomic and molecular physics
Maurice R. Kibler 1
(2004)

In this paper the dynamical noninvariance group SO(4,2) for a hydrogen-like atom is derived through two different approaches. The first one is by an established traditional ascent process starting from the symmetry group SO(3). This approach is presented in a mathematically oriented original way with a special emphasis on maximally superintegrable systems, N-dimensional extension and little groups. The second approach is by a new symmetry descent process starting from the noninvariance dynamical group Sp(8,R) for a four-dimensional harmonic oscillator. It is based on the little known concept of a Lie algebra under constraints and corresponds in some sense to a symmetry breaking mechanism. This paper ends with a brief discussion of the interest of SO(4,2) for a new group-theoretical approach to the periodic table of chemical elements. In this connection, a general ongoing programme based on the use of a complete set of commuting operators is briefly described. It is believed that the present paper could be useful not only to the atomic and molecular community but also to people working in theoretical and mathematical physics.
1:  Institut de Physique Nucléaire de Lyon (IPNL)
CNRS : UMR5822 – IN2P3 – Université Claude Bernard - Lyon I
Physics/Quantum Physics

Physics/Mathematical Physics

Physics/Physics/Atomic Physics
dynamical noninvariance groups – SO(4 – 2) – Sp(8 – R) – hydrogen-like atom – maximally superintegrable systems – four-dimensional harmonic oscillator – Lie algebra under constraints – periodic table
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