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Applied Physics Letters 100 (2012) 031903
On the entanglement of electrostriction and non-linear piezoelectricity in non-centrosymmetric materials
Laurent Pedesseau 1, Claudine Katan 1, 2, Jacky Even 1
(2012-01-17)

An extended and complete thermodynamical model of third-order electro-elastic coupling is proposed with symmetry analyses and density functional theory (DFT) calculations to evaluate consistently the various linear and non-linear coefficients. It is shown that in non-centrosymmetric materials, electrostrictive and non-linear piezoelectric phenomena are strongly coupled, except for materials crystallizing in a cubic lattice associated to the 432 point group. Thorough numerical results are given for GaN and AlN compounds in the Würtzite structure. Electrostriction dominates, but non-linear elasticity and non-linear piezoelectricity must be taken into account for strain evaluation whereas non-linear piezoelectricity yields a significant correction for electric field.
1:  Fonctions Optiques pour les Technologies de l'informatiON (FOTON)
CNRS : UMR6082 – Université de Rennes 1 – Institut National des Sciences Appliquées (INSA) : - RENNES – Ecole Nationale Supérieure des Sciences Appliquées et de Technologie (ENSSAT) – PRES Université Européenne de Bretagne [UEB] – Télécom Bretagne
2:  Chimie et Photonique Moléculaires (CPM)
CNRS : UMR6510 – Université de Rennes 1
FOTON Optoélectronique Hétéroépitaxie et Matériaux (OHM)
Engineering Sciences/Optics / Photonic

Physics/Condensed Matter/Materials Science

Engineering Sciences/Materials

Physics/Physics/Chemical Physics
aluminium compounds – crystallisation – density functional theory – elasticity – electrostriction – gallium compounds – III-V semiconductors – piezoelectric semiconductors – piezoelectricity – wide band gap semiconductors
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