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Friction Properties of Carbon Nano-Onions from Experiment and Computer Simulations
Joly-Pottuz L., Bucholz E.W., Matsumoto N., Philipot S.R., Sinnott S.B., Ohmae N., Martin J.M.
Tribology Letters 37 (2010) 75-81 - http://hal.archives-ouvertes.fr/hal-00587181
Articles dans des revues avec comité de lecture
Sciences de l'ingénieur/Matériaux
Friction Properties of Carbon Nano-Onions from Experiment and Computer Simulations
Lucile Joly-Pottuz 1, 2, E.W. Bucholz 3, N. Matsumoto 4, S.R. Philipot 3, S.B. Sinnott 3, N. Ohmae 4, J.M. Martin 2
1 :  Matériaux, ingénierie et sciences (MATEIS)
http://www.insa-lyon.fr/mateis/
CNRS : UMR5510 – Institut National des Sciences Appliquées (INSA) - Lyon
Bâtiment Blaise Pascal 7, avenue Jean Capelle 69621 VILLEURBANNE CEDEX
France
2 :  Laboratoire de Tribologie et Dynamique des Systèmes (LTDS)
http://ltds.ec-lyon.fr/
CNRS : UMR5513 – Ecole Centrale de Lyon – Ecole Nationale d'Ingénieurs de Saint Etienne
36 Avenue Guy de Collongue, 69134 Ecully Cedex
France
3 :  Department of Materials Science and Engineering [University of Florida]
University of Florida
PO Box 116400, Gainesville, Florida 32611
États-Unis
4 :  Department of Mechanical Engineering (DEPARTMENT OF MECHANICAL ENGINEERING)
Kobe University
Faculty of Engineering, Rokkodai, Nada, Kobe 657-8501
Japon
The carbon nano-onion can be considered as a new kind of interesting lubricating nanoparticle. Used as lubricant additives, carbon nano-onions lead to a strong reduction of both friction and wear, even at low temperature. To better elucidate the mechanisms by which these processes occur, coupled experimental and computational investigations are carried out. In addition, it is found that lubricious iron oxide nanoparticles are generated in the core of the steel contact through mechanisms that are not yet known. The molecular dynamics simulations of carbon onions placed between sliding diamond-like carbon surfaces at high contact pressure indicate that the lubrication mechanism of the onions is based on a coupled process of rolling and sliding inside the contact area. We conclude that most of carbon onions seem to remain intact under friction processes and do not generate graphitic planes, which is in contrast to the previously determined behavior of MoS2 fullerenes that are mainly exfoliated inside the contact area and liberate lubricating lamellar sheets of h-MoS2.
Anglais

Tribology Letters
Publisher Springer Verlag (Germany)
ISSN 1023-8883 (eISSN : 1573-2711)
internationale
01/2010
37
75-81